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电解质:多元系统的物化参数计算方法

ISBN:
1-56700-157-2 (打印)

电解质:多元系统的物化参数计算方法

G. G. Aseyev
Kharkiv State Institude of Culture, Kharkiv, Ukraine

描述

Original methods of the calculation of the physicochemical properties of multicomponent systems are presented. A great number of coefficients in calculation formulas and calculation errors are given. Coefficients for the calculation formulas for the most widely used electrolytes are shown in a high-temperature region. Each method of the determination of a physiochemical parameter is illustrated by calculation examples. Methods allow calculation of volumetric properties, equilibria in solutions, phase equilibria, thermal properties, solution properties, and transport phenomena.



368 pages, © 2001

目录:

FOREWORD
1 Methods of Calculation of Volumetric Properties
1.1 Density
1.2 Apparent Molar Volume
1.3 Apparent Molar Expansibility
1.4 Adiabatic Apparent Molar Compressibility
2 Equilibria in Solutions
2.1 Activity Coefficients in Multicomponent and Binary Solutions
2.2 Water Activity
2.3 Water Activity in a Multicomponent Solution Calculated from a Decrease of the Vapor Pressure over the Solution
2.4 Osmotic Coefficients
3 Phase Equilibria
3.1 Vapor Pressure over Multicomponent Solutions
3.2 Boiling Point
3.3 Freezing Point
4 Thermal Properties
4.1 Heat Capacity
4.2 Apparent Molar Heat Capacity
5 Properties of Solutions
5.1 Heat Conductivity
5.2 Surface Tension
6 Transport Phenomena
6.1 Dynamic viscosity
6.2 Electrical conductivity
6.3 Diffusion
Tables for Chapter 1
Tables for Chapter 2
Tables for Chapter 3
Tables for Chapter 4
Tables for Chapter 5
Tables for Chapter 6
References