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Electrolytes: Methods for Calculation of the Physicochemical Parameters of Multicomponent Systems

ISBN:
1-56700-157-2 (Print)

Electrolytes: Methods for Calculation of the Physicochemical Parameters of Multicomponent Systems

G. G. Aseyev
Kharkiv State Institude of Culture, Kharkiv, Ukraine

Description

Original methods of the calculation of the physicochemical properties of multicomponent systems are presented. A great number of coefficients in calculation formulas and calculation errors are given. Coefficients for the calculation formulas for the most widely used electrolytes are shown in a high-temperature region. Each method of the determination of a physiochemical parameter is illustrated by calculation examples. Methods allow calculation of volumetric properties, equilibria in solutions, phase equilibria, thermal properties, solution properties, and transport phenomena.



368 pages, © 2001

Table of Contents:

FOREWORD
1 Methods of Calculation of Volumetric Properties
1.1 Density
1.2 Apparent Molar Volume
1.3 Apparent Molar Expansibility
1.4 Adiabatic Apparent Molar Compressibility
2 Equilibria in Solutions
2.1 Activity Coefficients in Multicomponent and Binary Solutions
2.2 Water Activity
2.3 Water Activity in a Multicomponent Solution Calculated from a Decrease of the Vapor Pressure over the Solution
2.4 Osmotic Coefficients
3 Phase Equilibria
3.1 Vapor Pressure over Multicomponent Solutions
3.2 Boiling Point
3.3 Freezing Point
4 Thermal Properties
4.1 Heat Capacity
4.2 Apparent Molar Heat Capacity
5 Properties of Solutions
5.1 Heat Conductivity
5.2 Surface Tension
6 Transport Phenomena
6.1 Dynamic viscosity
6.2 Electrical conductivity
6.3 Diffusion
Tables for Chapter 1
Tables for Chapter 2
Tables for Chapter 3
Tables for Chapter 4
Tables for Chapter 5
Tables for Chapter 6
References