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Advances in Molten Salts

ISSN:
1-56700-142-4 (Print)

Phase Diagram Systematic Optimization of the REI2-MI (RE = Sm, Eu, Yb, M = Li, Na, K, Rb, Cs) Systems

Yimin Sun
Department of Physical Chemistry, University of Science & Technology Beijing,100083, P. R. China

Zhiyu Qiao
Department of Physical Chemistry, University of Science & Technology Beijing,100083, P. R. China

Abstract

The phase diagrams of the REI2-MI (RE = Sm, Eu, Yb, M = Li, Na, K, Rb, Cs) systems have been systematically optimized and calculated using CALPHAD approach. A set of thermodynamic functions has been optimized based on an interactive computer-assisted analysis. The calculated phase diagrams and optimized thermodynamical parameters are thermodynamically self-consistent