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Telecommunications and Radio Engineering

 

ISSN for PRINT: 0040-2508

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$4518.00

Issues per year:

20

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2006, Volume65

Issue 11-15

  475 pages  

DOI: 10.1615/TelecomRadEng.v65.i11   

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  • Comparative Analysis of Singlet and Excited States of Xanthene and Oxazine Dyes
  • P.G. Dalchenko
    V. Karazin National University of Kharkiv, 4, Svoboda Sq., Kharkiv, 61077, Ukraine

    M. I. Dzyubenko
    A. Usikov Institute of Radio Physics and Electronics, National Academy of Sciences of Ukraine 12, Academician Proskura St., Kharkov 61085, Ukraine

    V. F. Pedash
    V. Karazin National University of Kharkiv, 4, Svoboda Sq., Kharkiv, 61077, Ukraine

    Yu. F. Pedash
    V. Karazin National University of Kharkiv, 4, Svoboda Sq., Kharkiv, 61077, Ukraine


    ABSTRACT

    Calculations of the exited states of ionic forms of xanthene and oxazine dyes are carried out in the π-electron approximation. Electron transition energies, their polarization and electron density redistribution in the exited states are evaluated. The use of charge transfer numbers allowed us to establish a genetic bond of exited singlet states of xantene and oxazine compounds. Quantitative characteristics of the donor activity of substituents (amine- and oxy-groups) are obtained and their contribution to the formation of excited terms is determined with the use of localization numbers.

    DOI: 10.1615/TelecomRadEng.v65.i11.40

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