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Clean Air: International Journal on Energy for a Clean Environment

 

ISSN for PRINT: 1561-4417

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$451.00

Issues per year:

4

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2004, Volume5

Issue 3

  165 pages  

DOI: 10.1615/InterJEnerCleanEnv.v5.i3   

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  • DEVELOPMENT OF REDUCED CHEMICAL MECHANISMS FOR NITROGEN CONTAINING FUELS
  • T. Lovas
    Division of Combustion Physics, Lund Institute of Technology, PO Box 118, S-22100 Lund, Sweden

    D. Nilsson
    Division of Combustion Physics, Lund Institute of Technology, PO Box 118, S-22100 Lund, Sweden

    F. Mauss
    Division of Combustion Physics, Lund Institute of Technology, PO Box 118, S-22100 Lund, Sweden


    ABSTRACT

    A method for automatic reduction of reaction mechanisms has been developed and applied to a homogeneous model of a staged combustor simulation using a sequence of a PSR (Perfectly Stirred Reactor) and a PFR (Plug Flow Reactor) fuelled with ethylene (C2H4) doped with monomethylamine (CH3NH2) as a model compound for fuel bound nitrogen. A measure of species' lifetimes combined with the species' sensitivity is called the Level of Importance (LOI) and species with a LOI lower than a specified limit are selected as steady states. The original mechanism is reduced to a minimum of 22 species. It is found that the error in NO mole fractions relative to the detailed case amounts to single percentage units up to a lifetime limit of 10 μs (38 remaining species), and for the maximum achievable degree of reduction (22 remaining species), 3.9% in the PSR and 4.0% after the PFR.

    DOI: 10.1615/InterJEnerCleanEnv.v5.i3.70

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