A.
Kather K.
Mieske C.
Hermsdorf M.
Klostermann R.
Eggers D.
Kopke ABSTRACT The Oxyfuel process is one of the promising options for carbon capture and storage from fossil fuel power plants. It is based on the approved steam power process and therefore will profit from its high reliability and efficiency. The Oxyfuel process proposes the combustion of coal in an atmosphere of oxygen and recirculated flue gas, and will provide a flue gas containing up to 90 vol % of CO2. By means of a cryogenic liquefaction, a CO2 stream with a purity of almost 99% can be obtained. However, the implementation of the Oxyfuel process and other CCS technologies is dependent on legal matters concerning the amount of impurities allowed for the storage sites. The additional units, such as the air separation unit and the CO2 separation plant, will have a considerable power demand, leading to an efficiency drop of more than ten percentage points. This efficiency loss can be reduced to approximately eight percentage points by an optimized process leading to a net electrical efficiency of 38% compared to the reference plant with 46%.
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