Physical Chemistry of Aqueous Systems: Meeting the Needs of Industry
ISBN Print: 978-1-56700-034-4
ISBN Online: 978-1-56700-445-8
STANDARD PARTIAL MOLAR HEAT CAPACITIES AND VOLUMES OF AQUEOUS DIVALENT AND TRIVALENT IONS FROM MEASUREMENTS NEAR 25°C
DOI: 10.1615/ICPWS-1994.650
pages 511-517
Abstrakt
Apparent molar heat capacities and volumes for a number of trivalent and divalent ions have been measured in our laboratory over the range 10 to 65°C. This paper presents a summary of recent results and evaluates the success of the revised Helgeson-Kirkham-Flowers model and a model based on solvent density in predicting the heat capacity and volume functions over a wide temperature range.
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