Organometallic Synthesis in Room-Temperature Chloroaluminate (Ⅲ) Ionic Liquids

Crofts, D.; Dyson, P. J.; Sanderson, K. M.; Srinivasan, N.; Welton, T.

Advances in Molten Salts

ISBN Druckformat: 1-56700-142-4

Organometallic Synthesis in Room-Temperature Chloroaluminate (Ⅲ) Ionic Liquids

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D. Crofts Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK

P. J. Dyson Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK

K. M. Sanderson Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK

N. Srinivasan Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK

T. Welton Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK

Abstrakt

The ionic liquid system [bmim]Cl-AlCl₃ ([bmim]⁺ = l-butyl-3-methylimidazolium cation) is used as a combination of solvent and Lewis acid catalyst in a number of carbon-carbon and metal-carbon bond-forming reactions. Friedel-Crafts reactions of ferrocene and ruthenocene, as a function of acidity of the ionic liquid are reported. The formation of cationic metal-arene complexes under similar conditions is also reported.

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