Advances in Molten Salts

ISBN Print: 1-56700-142-4

Electrical conductivity of molten system KCl-CeCl3-Ce

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A. Red'kin The Institute of High-Temperature Electrochemistry C.Kovalevskaya Str.20, Ekaterinburg 620219, Russia

O. Tkatcheva The Institute of High-Temperature Electrochemistry C.Kovalevskaya Str.20, Ekaterinburg 620219, Russia

V. Shishkin The Institute of High-Temperature Electrochemistry C.Kovalevskaya Str.20, Ekaterinburg 620219, Russia

V. Khokhlov Molten Salts Laboratory Institute of High-Temperature Electrochemistry, 20 S.Kovalevskaya Str., 620219 Ekatherinburg, Russia

Abstract

The electrical conductivity of CeCl3-Ce and CeCl3-KCl(25 mol.%)-Ce systems has been measured as a function of Ce concentration and temperature. The cell of Eager's type with molybdenum crucible and two parallel electrodes was used. The electrical conductivity of system under investigation was found to decrease greatly with potassium chloride addition.

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