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Advances in Molten Salts

ISBN:
1-56700-142-4 (印刷)

Anodic process on a glassy carbon electrode in KCl-LiCl and KCl-LiCl-NaCl-CsCl melts

A. P. Apisarov
The Institute of High Temperature Electrochemistry Ural Branch of Russian Academy of Sciences, S. Kovalevskoy 20, 620219 Ecaterinburg, Russian Federation

V. N. Nekrasov
The Institute of High Temperature Electrochemistry Ural Branch of Russian Academy of Sciences, S. Kovalevskoy 20, 620219 Ecaterinburg, Russian Federation

P. A. Arhipov
The Institute of High Temperature Electrochemistry Ural Branch of Russian Academy of Sciences, S. Kovalevskoy 20, 620219 Ecaterinburg, Russian Federation

要約

In present work we make an attempt to extend a temperature diapason of anodic processes investigations in alkaline chloride melts in low temperature region. We have selected a low melting systems: KCl-LiCl and KCl-LiCl-NaCl-CsCl (Tmelt= 546 K [1]) for this purpose. The working diapason of temperatures was from 573 to 873 K. Experiments were carried out using chronopotentiometry. We used stationary and non-stationary (transients) methods. We disclosed the detailed description of this methods in ours previous articles [2,3]. A gas-diffusion chloride electrode was used as counterelectrode. We used a chlorine/chloride reference electrode and a glassy carbon working electrode .We worked under a dry chlorine atmosphere in all cases.